Two-phase quality (Q)

In the two-phase region (liquid + vapor), a fluid state is often described by pressure and vapor quality Q. Quality is a convenient way to indicate how much of the mixture is vapor versus liquid.

Definition

Vapor quality Q is typically defined as the mass fraction of vapor in a saturated mixture:

Q = 0 → saturated liquid, Q = 1 → saturated vapor.

Why PT can be ambiguous on the saturation line

For a pure fluid (and many pseudo-pure refrigerants), at a given saturation pressure, the saturation temperature is fixed (and vice versa). That means many distinct two-phase states share the same P and T but have different qualities, enthalpy, density, and other properties. To make the state unique, you need a third variable—often quality.

Important note on refrigerant blends

Many refrigerants are blends. For zeotropic blends, “saturation” can span a temperature range at a given pressure (bubble point vs dew point), also known as temperature glide. In those cases, pressure + temperature can be ambiguous in a different way, and “quality” may not map as cleanly as it does for a pure fluid. When working with blends, follow the application’s measurement conventions and use the input pair that best matches what you actually know (for example, P–h or P–s).

Practical guidance